Issue 45, 2017, Issue in Progress
From the journal:

RSC Advances

Synthesis of α-aminophosphonates using solvate ionic liquids†

Daniel J. Eyckensa  and  Luke C. Henderson ORCID logo *a  

* Corresponding authors

a Institute for Frontier Materials, Deakin University, 75 Pigdons Road, Geelong, Victoria, Australia
E-mail: luke.henderson@deakin.edu.au

Abstract

A range of α-aminophosphonates were accessed in high yields and very rapidly, using solvate ionic liquids as the reaction media. Reactions typically required less than 10 minutes to go to completion and precipitation of these products into water excludes the use of traditional work up procedures, giving the products in very high crude purity. Excellent functional group tolerance for both the aldehyde and amine reaction partners was observed, and a range of bis-aminophosphonates derived from aromatic diamines were also accessed in high yield and purity.

Graphical abstract: Synthesis of α-aminophosphonates using solvate ionic liquids

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7RA04407K
Article type
Paper
Submitted
19 Apr 2017
Accepted
18 May 2017
First published
25 May 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 27900-27904

Permissions

Request permissions

Synthesis of α-aminophosphonates using solvate ionic liquids

D. J. Eyckens and L. C. Henderson, RSC Adv., 2017, 7, 27900 DOI: 10.1039/C7RA04407K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements