Issue 26, 2013
From the journal:

RSC Advances

The rhodium-catalysed synthesis of pyrrolidinone-substituted (trialkylsilyloxy)acrylic esters†

Daniel L. Priebbenowa  and  Carsten Bolm*a  

* Corresponding authors

a Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: carsten.bolm@oc.rwth-aachen.de
Fax: +49 241-8092391
Tel: +49 241-8094675

Abstract

A method for the preparation of novel pyrrolidine substituted (trialkylsilyloxy)acrylic esters has been developed. The protocol involves a rhodium-catalysed O-insertion/rearrangement reaction between N-functionalised 2-pyrrolidinones and α-silyl α-diazoacetates to form the corresponding acrylic esters in moderate to high yields.

Graphical abstract: The rhodium-catalysed synthesis of pyrrolidinone-substituted (trialkylsilyloxy)acrylic esters

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Article information

DOI
https://doi.org/10.1039/C3RA41527A
Article type
Paper
Submitted
28 Mar 2013
Accepted
07 May 2013
First published
07 May 2013

RSC Adv., 2013,3, 10318-10322

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The rhodium-catalysed synthesis of pyrrolidinone-substituted (trialkylsilyloxy)acrylic esters

D. L. Priebbenow and C. Bolm, RSC Adv., 2013, 3, 10318 DOI: 10.1039/C3RA41527A

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