Issue 8, 1994
From the journal:

Analytical Proceedings including Analytical Communications

Observations of the chemiluminescent background emission from the reaction of bis(2,4,6-trichlorophenyl) oxalate with hydrogen peroxide in aqueous tetrahydrofuran (1 + 1)

Neil W. Barnett,   Raelene N. Evans  and  Richard A. Russell  

Abstract

The chemiluminescent emission given by bis(2,4,6-trichlorophenyl) oxalate and hydrogen peroxide, in the absence of a fluorophore, has been recorded in aqueous tetrahydrofuran (1 + 1) over the wavelength range 300–600 nm and the pH range 6.8–12.0. This emission is enhanced by the addition of alkyl halides and base catalysts such as imidazole and triethylamine. A mechanism accounting for the origin of this chemiluminescence is discussed together with is implications for analytical applications.

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Article information

DOI
https://doi.org/10.1039/AI9943100241
Article type
Paper

Anal. Proc., 1994,31, 241-244

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Observations of the chemiluminescent background emission from the reaction of bis(2,4,6-trichlorophenyl) oxalate with hydrogen peroxide in aqueous tetrahydrofuran (1 + 1)

N. W. Barnett, R. N. Evans and R. A. Russell, Anal. Proc., 1994, 31, 241 DOI: 10.1039/AI9943100241

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