Elsevier

Polymer

Volume 68, 26 June 2015, Pages 25-34
Polymer

Epoxy nanocomposites containing magnetite-carbon nanofibers aligned using a weak magnetic field

https://doi.org/10.1016/j.polymer.2015.04.080Get rights and content
Under a Creative Commons license
open access

Highlights

  • Magnetite-carbon nanofibers (Fe3O4@CNFs) were fabricated by co-precipitation.

  • Fe3O4@CNFs were aligned in an epoxy resin by a low magnetic field (∼50 mT).

  • Greatly improved electrical conductivity was obtained in the alignment direction.

  • Significantly higher fracture toughness was achieved by aligning the Fe3O4@CNFs normal to the crack surface.

Abstract

Novel magnetite-carbon nanofiber hybrids (denoted by “Fe3O4@CNFs”) have been developed by coating carbon nanofibers (CNFs) with magnetite nanoparticles in order to align CNFs in epoxy using a relatively weak magnetic field. Experimental results have shown that a weak magnetic field (∼50 mT) can align these newly-developed nanofiber hybrids to form a chain-like structure in the epoxy resin. Upon curing, the epoxy nanocomposites containing the aligned Fe3O4@CNFs show (i) greatly improved electrical conductivity in the alignment direction and (ii) significantly higher fracture toughness when the Fe3O4@CNFs are aligned normal to the crack surface, compared to the nanocomposites containing randomly-oriented Fe3O4@CNFs. The mechanisms underpinning the significant improvements in the fracture toughness have been identified, including interfacial debonding, pull-out, crack bridging and rupture of the Fe3O4@CNFs, and plastic void growth in the polymer matrix.

Keywords

Carbon nanofibers
Magnetic field alignment
Epoxy nanocomposites

Cited by (0)