Skip to main content
Log in

Dynamic mechanical behavior of a Zr-based bulk metallic glass during glass transition and crystallization

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

The dynamic mechanical behaviors of the Zr41Ti14Cu12.5Ni8Be22.5Fe2 bulk metallic glass (BMG) during continuous heating at a constant rate were investigated. The glass transition and crystallization of the Zr-based BMG were thus characterized by the measurements of storage modulus E′ and internal friction Q −1. It was found that the variations of these dynamic mechanical quantities with temperature were interrelated and were well in agreement with the DSC trace obtained at the same heating rate. The origin of the first peak in the internal friction curve was closely related to the dynamic glass transition and subsequent primary crystallization. Moreover, it can be well described by a physical model, which can characterize atomic mobility and mechanical response of disordered condense materials. In comparison with the DSC trace, the relative position of the first internal friction peak of the BMG was found to be dependent on its thermal stability against crystallization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Inoue A., Zhang T., and Masumoto T., Production of amorphous cylinder and sheet of La55Al25Ni20 alloy by a metallic mold casting method, Mater. Trans. JIM, 1990, 31(5): 425.

    CAS  Google Scholar 

  2. Inoue A., Kato A., Zhang T., Kim S.G., and Masumoto T., Mg-Cu-Y amorphous alloys with high mechanical strengths produced by a metallic mold casting method, Mater. Trans. JIM, 1991, 32(7): 609.

    CAS  Google Scholar 

  3. Zhang T., Inoue A., and Masumoto T., Amorphous Zr-Al-TM (TM=Co, Ni, Cu) alloys with significant supercooled liquid region of over 100 K, Mater. Trans. JIM, 1991, 32(11): 1005.

    CAS  Google Scholar 

  4. Peker A. and Johnson W.L., A highly processing metallic glass: Zr41.5Ti13.8Cu12.5Ni10Be22.5, Appl. Phys. Lett., 1993, 63(17): 2342.

    Article  ADS  Google Scholar 

  5. Scarfone R. and Sinning H.R., A mechanical spectroscopy study of the Zr69.5Cu12Ni11Al7.5 alloy, J. Alloys Compd., 2000, 310(1–2): 229.

    Article  CAS  Google Scholar 

  6. Pelletier J.M., Perez J., and Soubeyroux J.L., Physical properties of bulk amorphous glasses: influence of physical aging and onset of crystallization, J. Non Cryst. Solids, 2000, 274(1–3): 301.

    Article  ADS  CAS  Google Scholar 

  7. Bobrov O.P., Khonik V.A., Laptev S.N., and Yazvitsky M.Y., Comparative internal friction study of bulk and ribbon glassy Zr52.5Ti5Cu17.9Ni14.6Al10, Scripta Mater., 2003, 49(3): 255.

    Article  CAS  Google Scholar 

  8. Aboki T.A.M., Masse M.L., Dezellus A., Ochin P., and Portier R., First investigations on twin-rolled Zr59Cu20Al10Ni8Ti3 bulk amorphous alloy by mechanical spectroscopy, Mater. Sci. Eng. A, 2004, 370(1–2): 330.

    Google Scholar 

  9. Rambousky R., Moske M., and Samwer K., Structural relaxation and viscous flow in amorphous ZrAlCu, Z. Phys. B, 1996, 99(3): 387.

    Article  ADS  CAS  Google Scholar 

  10. Zhang B., Zu F.Q., Zhen K., Shui J.P., and Wen P., Internal friction behaviours in Zr57Al10Ni12.4Cu15.6Nb5 bulk metallic glass, J. Phys. Condens. Matter, 2002, 14(32): 7461.

    Article  ADS  CAS  Google Scholar 

  11. Hiki Y., Yagi T., Aida T., and Takeuchi S., Low-frequency high-temperature internal friction of bulk metallic glasses, J. Alloys Compd., 2003, 355(1–2): 42.

    Article  CAS  Google Scholar 

  12. Perera D.N. and Tsai A.P., Comparing the dynamic tensile response of supercooled Pd48Ni32P20 and Pt60Ni15P25, J. Phys. D, 1999, 32(22): 2933.

    Article  CAS  Google Scholar 

  13. Schröter K. and Donth E., Comparison of shear response with other properties at the dynamic glass transition of different glassformers, J. Non Cryst. Solids, 2000, 307–310: 270.

    Google Scholar 

  14. Suh D., Asoka-Kumar P. and Dauskardt R.H., The effects of hydrogen on viscoelastic relaxation in Zr-Ti-Ni-Cu-Be bulk metallic glasses: implications for hydrogen embrittlement, Acta. Mater., 2002, 50(3): 537.

    Article  CAS  Google Scholar 

  15. Lee M.L., Li Y., Feng Y.P., and Carter W.C., Frequency-dependent complex modulus at the glass transition in Pd40Ni10Cu30P20 bulk amorphous alloys, Phys. Rev. B, 2003, 67(13): 132201–1.

    Article  ADS  Google Scholar 

  16. Wen P., Zhao D.Q., Pan M.X., and Wang W.H., Relaxation of metallic Zr46.25Ti8.25Cu7.5Ni10Be27.5 bulk lass-forming supercooled liquid, Appl. Phys. Lett., 2004, 84(15): 2790.

    Article  ADS  CAS  Google Scholar 

  17. Sinning H.R., Low-frequency internal friction of metallic glasses near T g A critique of the use of the torsion pendulum, J. Non Cryst. Solids, 1989, 110(2–3): 195.

    Article  ADS  CAS  Google Scholar 

  18. Belko V.N., Darinskii B.M., Postnikov V.S., and Sharshakov I.M., Internal friction during diffusionless phase transformations in CoNi alloys, Fiz. Met. Metalloved., 1969, 27(1): 141.

    CAS  Google Scholar 

  19. Perez J., Study of polymer materials by mechanical spectroscopy methods, Polym. Sci. Ser. B, 1998, 40(1–2): 17.

    Google Scholar 

  20. Perez J., Cavaille J.Y., and David L., New experimental features and revisiting the α and β mechanical relaxation in glasses and glass-forming liquids, J. Mol. Struct., 1999, 479(2–3): 183.

    Article  CAS  Google Scholar 

  21. Gauthier C., Pelletier J.M., David L., Vigier G., and Perez J., Relaxation of non-crystalline solids under mechanical stress, J. Non Cryst. Solids, 2000, 274(1–3): 181.

    Article  ADS  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qing Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chao, Q., Wang, Q. & Dong, Y. Dynamic mechanical behavior of a Zr-based bulk metallic glass during glass transition and crystallization. Rare Metals 28, 72–76 (2009). https://doi.org/10.1007/s12598-009-0014-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-009-0014-6

Keywords

Navigation