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Two 3D supramolecular frameworks assembled from the dinuclear building block: A crystallographic evidence of carboxylate(O)…π interaction

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Abstract

Figure. In two new complexes of Mn(II) and Zn(II), it has been observed that carboxylate (O)…π interactions played a crucial role in the organization of supramolecular structure and that carboxylate (O)…π interactions also somehow controlled by the C-H…π interactions, which is achieved by proper modulation of the linkers.

In two new complexes of Mn(II) and Zn(II), it has been observed that carboxylate (O)…π interactions played a crucial role in the organization of supramolecular structure and that carboxylate (O)…π interactions also somehow controlled by the C-H…π interactions, which is achieved by proper modulation of the linkers.

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Acknowledgements

S M and S R thank UGC for fellowship. D G thanks JNCASR for visiting fellowship programme. T K M thanks DST, Government of India, for the financial support (fast track proposal).

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Authors and Affiliations

  1. Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560 064, India

    SUDIP MOHAPATRA, SYAMANTAK ROY & TAPAS KUMAR MAJI

  2. Department of Chemistry, Jadavpur University, Jadavpur, Kolkata, 700 032, India

    DEBAJYOTI GHOSHAL

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  1. SUDIP MOHAPATRA
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  2. SYAMANTAK ROY
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  3. DEBAJYOTI GHOSHAL
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  4. TAPAS KUMAR MAJI
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Correspondence to TAPAS KUMAR MAJI.

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Supplementary Information

CCDC 752075 and 752076 contain the supplementary crystallographic data for 1 and 2, respectively. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre.

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MOHAPATRA, S., ROY, S., GHOSHAL, D. et al. Two 3D supramolecular frameworks assembled from the dinuclear building block: A crystallographic evidence of carboxylate(O)…π interaction. J Chem Sci 126, 1153–1161 (2014). https://doi.org/10.1007/s12039-014-0674-0

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