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Performance enhancement of the anti-corrosion coating based on Ce3+-polyaniline–montmorillonite composite/epoxy-ester system

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Abstract

Herein we report on the Ce3+-5-sulfosalicylic acid dihydrate-doped polyaniline/montmorillonite (Ce3+-PANI/MMT) composite prepared via in situ intercalation polymerization and the cation-exchange method. The as-prepared samples were characterized by the scanning electron microscope, transmission electron microscope, X-ray diffraction analysis, and Fourier transform infrared spectrometer. The release of Ce3+ ions was detected by the immersion test and the solution analysis method. The anti-corrosion performance of the coatings was evaluated by the corrosion test, open-circuit potential analysis, the potentiodynamic polarization curve, and electrochemical impedance spectroscopy in 3.5 wt% NaCl aqueous solution. The results showed that the Ce3+-PANI/MMT composite had better anti-corrosion effects along the coating defects.

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Acknowledgments

Grants from the Science and Technology Commission of Shanghai Municipality (12DZ2280300, 14DZ0500700, 14DZ2261000) are appreciated.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, School of Environmental and Chemical Engineering, Shanghai University of Electric Power, Shanghai, 200090, People’s Republic of China

    Zhen Hua Zhang, Da Quan Zhang, Li Hua Zhu & Li Xin Gao

  2. Institute for Frontier Materials, Deakin University, Geelong, VIC, 3216, Australia

    Tong Lin

  3. Merchant Marine College, Shanghai Martime University, Shanghai, 201306, People’s Republic of China

    Wen Ge Li

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  1. Zhen Hua Zhang
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Correspondence to Da Quan Zhang.

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Zhang, Z.H., Zhang, D.Q., Zhu, L.H. et al. Performance enhancement of the anti-corrosion coating based on Ce3+-polyaniline–montmorillonite composite/epoxy-ester system. J Coat Technol Res 14, 1083–1093 (2017). https://doi.org/10.1007/s11998-016-9897-y

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