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In Situ Synthesis of TiC-Fe Composite Overlays from Low Cost TiO2 Precursors Using Plasma Transferred Arc Deposition

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Abstract

A direct conversion of TiO2 into TiC during plasma transferred arc deposition is a cheap and novel approach to produce wear resistant coatings. The present study explored the use of a low cost titanium ore as precursor for titanium carbide in metal matrix composite overlays. The deposited layers were characterized using optical microscopy, scanning electron microscopy, x-ray diffraction and microhardness testing. A carbothermic reduction of the titanium oxides took place during the deposition of the coating by plasma transferred arc. The overlays produced in this way consisted of fine titanium carbides evenly dispersed in an iron matrix. The opportunities and limitations of this approach are discussed.

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References

  1. P. Skarvelis, A. Rokanopoulou, and G.D. Papadimitriou, Formation of TiS and Ti4C2S2 in Steel Matrix Composites Prepared by the Plasma Transferred Arc (PTA) Technique Using TiS2 and TiC Powders, Tribol. Int., 2013, 66, p 44-48

    Article  Google Scholar 

  2. F.O. Drozda, P.A. Pianaro, and A.S.C.M. d’Oliveira, In-Situ Processing of Alumina Layers by PTA, Mater Sci Tech, Oct 16-20, 2011 (Columbus, OH) Association of Iron and Steel Technology, 2011, p 1721-1728

  3. A. Emamian, S.F. Corbin, and A. Khajepour, Effect of Laser Cladding Process Parameters on Clad Quality and In Situ Formed Microstructure of Fe-TiC Composite Coatings, Surf. Coat. Technol., 2010, 205(7), p 2007-2015

    Article  Google Scholar 

  4. X. Wu and G. Chen, Microstructure and Wear Resistance of In Situ TiCp Composite Coating by Laser Cladding, J. Mater. Sci. Technol., 1999, 15(3), p 233-238

    Google Scholar 

  5. K. Upadhya, J.J. Moore, and K.J. Reid, Application of Thermodynamic and Kinetic Principles in the Reduction of Metal Oxides by Carbon in a Plasma Environment, Metall. Trans. B, 1986, 17(1), p 197-207

    Article  Google Scholar 

  6. Materials Selection and Design, ASM Handbook, vol 20, G. Dieter, Ed., ASM International, Materials Park, OH, 1990, p 427

  7. N.J. Welham and J.S. Williams, Carbothermic Reduction of Ilmenite (FeTiO3) and Rutile (TiO2), Metall. Mater. Trans. B, 1999, 30(6), p 1075-1081

    Article  Google Scholar 

  8. W. Gruner, S. Stolle, and K. Wetzig, Formation of CO x Species During the Carbothermal Reduction of Oxides of Zr, Si, Ti, Cr, W, and Mo, Int. J. Refract. Met. Hard Mater., 2000, 18(2-3), p 137-145

    Article  Google Scholar 

  9. K. Jayasankar, A. Mandal, A. Pany, and P.S. Mukherjee, Synthesis of Fe-TiC In Situ Composites by Plasma Smelting of Ilmenite, Mater. Manuf. Process., 2011, 26(10), p 1330-1334

    Article  Google Scholar 

  10. B.S. Terry and O. Chinyamakobvu, Carbothermic Reduction of Ilmenite and Rutile as Means of Production of Iron Based Ti(O, C) Metal Matrix Composites, Mater. Sci. Technol., 1991, 7(9), p 842-848

    Article  Google Scholar 

  11. R.K. Galgali, H.S. Ray, and A.K. Chakrabarti, A study on Carbothermic Reduction of Ilmenite Ore in a Plasma Reactor, Metall. Mater. Trans. B, 1998, 29(6), p 1175-1180

    Article  Google Scholar 

  12. N. Setoudeh, A. Saidi, and N.J. Welham, Carbothermic Reduction of Anatase and Rutile, J. Alloy. Compd., 2005, 390(1-2), p 138-143

    Article  Google Scholar 

  13. R. Koc and J.S. Folmer, Carbothermal Synthesis of Titanium Carbide Using Ultrafine Titania Powders, J. Mater. Sci., 1997, 32(12), p 3101-3111

    Article  Google Scholar 

  14. X. Chen, Y. Li, Y. Li, J. Zhu, S. Jin, L. Zhao, Z. Lei, and X. Hong, Carbothermic Reduction Synthesis of Ti(C, N) Powder in the Presence of Molten Salt, Ceram. Int., 2008, 34(5), p 1253-1259

    Article  Google Scholar 

  15. Y. Chen, T. Hwang, M. Marsh, and J.S. Williams, Mechanically Activated Carbothermic Reduction of Ilmenite, Metall. Mater. Trans. A, 1997, 28(5), p 1115-1121

    Article  Google Scholar 

  16. N. Setoudeh, A. Saidi, and N.J. Welham, Effect of Elemental Iron and Gas Atmosphere on the Carbothermic Reduction of Rutile, J. Alloy. Compd., 2006, 419(1-2), p 247-250

    Article  Google Scholar 

  17. W. Sen, H. Sun, B. Yang, B. Xu, W. Ma, D. Liu, and Y. Dai, Preparation of Titanium Carbide Powders by Carbothermal Reduction of Titania/Charcoal at Vacuum Condition, Int. J. Refract. Met. Hard Mater., 2010, 28(5), p 628-632

    Article  Google Scholar 

  18. M. Suzuki, S. Sodeoka, T. Inoue, and K. Ueno, Basic Research for Reactive Plasma Spraying of TiO2, ITSC, May 25-29, 1998 (Nice), ASM Thermal Spray Society, 1998, p 1443-1448

  19. P.V. Ananthapadmanabhan and P.R. Taylor, Titanium Carbide-Iron Composite Coatings by Reactive Plasma Spraying of Ilmenite, J. Alloy. Compd., 1999, 287(1-2), p 121-125

    Article  Google Scholar 

  20. S. Corujeira Gallo, Low Cost Precursors for In Situ Synthesis of Composite Materials Using Plasma Transferred Arc Welding, PRICM8, Aug 4-9, 2013 (Waikoloa, HI), TMS, 2013, p 2345-2351

  21. C.I. Lin, The Effect of Alkali Salt Catalyst on the Carbothermic Reduction of Nickel Oxide, Metall. Trans. B, 1988, 19(3), p 685-686

    Article  Google Scholar 

  22. J.W. Kim and H.G. Lee, Thermal and Carbothermic Decomposition of Na2CO3 and Li2CO3, Metall. Mater. Trans. B, 2001, 32(1), p 17-24

    Article  Google Scholar 

  23. K.T. Scott and J.L. Woodhead, Gel-Processed Powders for Plasma Spraying, Thin Solid Films, 1982, 95(3), p 219-225

    Article  Google Scholar 

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Correspondence to Santiago Corujeira Gallo.

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Corujeira Gallo, S., Alam, N. & O’Donnell, R. In Situ Synthesis of TiC-Fe Composite Overlays from Low Cost TiO2 Precursors Using Plasma Transferred Arc Deposition. J Therm Spray Tech 23, 551–556 (2014). https://doi.org/10.1007/s11666-013-0052-3

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  • DOI: https://doi.org/10.1007/s11666-013-0052-3

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