Abstract
The nucleation and growth of Au and Ag nanoparticles on rutile TiO2(110)–(1 × 1) surfaces in different oxidation states is studied by means of photoelectron spectroscopy (PES) and scanning tunneling microscopy (STM). Au and Ag nanoparticles were found to bind much more strongly to oxidized TiO2(110) model supports than to reduced TiO2(110) surfaces, as directly revealed by STM. Detailed PES studies addressing small Au and Ag particles complete this picture and show that the PES core level spectra acquired on Au/TiO2(110) and Ag/TiO2(110) can be best described by fitting with two binding energy (BE) components. Particularly for coverages in the sub-monolayer regime and for depositions at low temperatures (100 K) the PES core level spectra must be fitted with at least two BE components. The higher BE component is attributed to atoms at the interface between the metal clusters and the TiO2(110) support. For Au/TiO2(110), the two BE components were evident in the core level spectra for higher coverage than for Ag/TiO2(110), consistent with different growth modes for Au (initially 2D) and Ag (3D) on TiO2(110). Finally, strong evidence for charge transfer from Ag nanoparticles to the TiO2(110) support is presented, whereas the charge transfer between Au nanoparticles and the TiO2(110) support is very small.
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Bäumer M, Freund HJ (1999) Prog Surf Sci 61:127
Campbell CT (2004) Science 306:234
Carp O, Huisman CL, Reller A (2004) Prog Solid State Chem 32:33
Fu Q, Wagner T (2007) Surf Sci Rep 62:431
Fujishima A, Zhang X, Tryk DA (2008) Surf Sci Rep 63:515
Henderson MA (2011) Surf Sci Rep 66:185
Kamat PV (2002) J Phys Chem B 106:7729
Haruta M, Yamada N, Kobayashi T, Iijima S (1989) J Catal 115:301
Bamwenda GR, Tsubota S, Nakamura T, Haruta M (1997) Catal Lett 44:83
Bond GC, Thompson DT (2000) Gold Bull 33:41
Valden M, Lai X, Goodman DW (1998) Science 281:1647
Yoon B, Häkkinen H, Landman U, Wörz AS, Antonietti JM, Abbet S, Judai K, Heiz U (2005) Science 307:403
Lee SS, Fan CY, Wu TP, Anderson SL (2004) J Am Chem Soc 126:5682
Turner M, Golovko VB, Vaughan OPH, Abdulkin P, Berenguer-Murcia A, Tikhov MS, Johnson BFG, Lambert RM (2008) Nature 454:981
Herranz T, Deng XY, Cabot A, Alivisatos P, Liu Z, Soler-Illia G, Salmeron M (2009) Catal Today 143:158
Schubert MM, Hackenberg S, van Veen AC, Muhler M, Plzak V, Behm RJ (2001) J Catal 197:113
Meyer R, Lemire C, Shaikhutdinov SK, Freund H (2004) Gold Bull 37:72
Matthey D, Wang JG, Wendt S, Matthiesen J, Schaub R, Lægsgaard E, Hammer B, Besenbacher F (2007) Science 315:1692
Rodriguez JA, Liu P, Hrbek J, Evans J, Pérez M (2007) Angew Chem Int Ed 46:1329
Herzing AA, Kiely CJ, Carley AF, Landon P, Hutchings GJ (2008) Science 321:1331
Hashmi ASK, Hutchings GJ (2006) Angew Chem Int Ed 45:7896
Chen MS, Goodman DW (2006) Catal Today 111:22
Haruta M, Daté M (2001) Appl Catal A Gen 222:427
Haruta M (2004) Gold Bull 37:27
Molina LM, Rasmussen MD, Hammer B (2004) J Chem Phys 120:7673
Janssens TVW, Clausen BS, Hvolbaek B, Falsig H, Christensen CH, Bligaard T, Nørskov JK (2007) Top Catal 44:15
Green IX, Tang WJ, Neurock M, Yates JT Jr (2011) Science 333:736
Fujita T, Guan PF, McKenna K, Lang XY, Hirata A, Zhang L, Tokunaga T, Arai S, Yamamoto Y, Tanaka N, Ishikawa Y, Asao N, Erlebacher J, Chen MW (2012) Nature Mater 11:775
Lin X, Yang B, Benia HM, Myrach P, Yulikov M, Aumer A, Brown MA, Sterrer M, Bondarchuk O, Kieseritzky E, Rocker J, Risse T, Gao HJ, Nilius N, Freund HJ (2010) J Am Chem Soc 132:7745
Okazaki K, Ichikawa S, Maeda Y, Haruta M, Kohyama M (2005) Appl Catal A Gen 291:45
Sanchez A, Abbet S, Heiz U, Schneider WD, Häkkinen H, Barnett RN, Landman U (1999) J Phys Chem A 103:9573
Wörz AS, Heiz U, Cinquini F, Pacchioni G (2005) J Phys Chem B 109:18418
Ricci D, Bongiorno A, Pacchioni G, Landman U (2006) Phys Rev Lett 97:036106
Xu Y, Mavrikakis M (2003) J Phys Chem B 107:9298
Giorgio S, Cabié M, Henry CR (2008) Gold Bull 41:167
Guzman J, Gates BC (2004) J Am Chem Soc 126:2672
Fu L, Wu NQ, Yang JH, Qu F, Johnson DL, Kung MC, Kung HH, Dravid VP (2005) J Phys Chem B 109:3704
Concepción P, Carrettin S, Corma A (2006) Appl Catal A Gen 307:42
Casaletto MP, Longo A, Martorana A, Prestianni A, Venezia AM (2006) Surf Interface Anal 38:215
Wang JG, Hammer B (2006) Phys Rev Lett 97:136107
Wang JG, Hammer B (2007) Top Catal 44:49
Veith GM, Lupini AR, Dudney NJ (2009) J Phys Chem C 113:269
Brown MA, Fujimori Y, Ringleb F, Shao X, Stavale F, Nilius N, Sterrer M, Freund HJ (2011) J Am Chem Soc 133:10668
Boccuzzi F, Chiorino A (2000) J Phys Chem B 104:5414
Schumacher B, Plzak V, Kinne M, Behm RJ (2003) Catal Lett 89:109
Willneff EA, Braun S, Rosenthal D, Bluhm H, Hävecker M, Kleimenov E, Knop-Gericke A, Schlögl R, Schroeder SLM (2006) J Am Chem Soc 128:12052
Zhang L, Persaud R, Madey TE (1997) Phys Rev B 56:10549
Lai X, St Clair TP, Valden M, Goodman DW (1998) Prog Surf Sci 59:25
Parker SC, Grant AW, Bondzie VA, Campbell CT (1999) Surf Sci 441:10
Cosandey F, Madey TE (2001) Surf Rev Lett 8:73
Chusuei CC, Lai X, Luo K, Goodman DW (2001) Top Catal 14:71
Howard A, Clark DNS, Mitchell CEJ, Egdell RG, Dhanak VR (2002) Surf Sci 518:210
Kim TS, Stiehl JD, Reeves CT, Meyer RJ, Mullins CB (2003) J Am Chem Soc 125:2018
Minato T, Susaki T, Shiraki S, Kato HS, Kawai M, Aika KI (2004) Surf Sci 566:1012
Chen M, Cai Y, Yan Z, Goodman DW (2006) J Am Chem Soc 128:6341
Okazawa T, Kohyama M, Kido Y (2006) Surf Sci 600:4430
Rodriguez JA, Evans J, Graciani J, Park JB, Liu P, Hrbek J, Sanz JF (2009) J Phys Chem C 113:7364
Porsgaard S, Jiang P, Borondics F, Wendt S, Liu Z, Bluhm H, Besenbacher F, Salmeron M (2011) Angew Chem Int Ed 50:2266
Dumbuya K, Cabailh G, Lazzari R, Jupille J, Ringel L, Pistor M, Lytken O, Steinrück HP, Gottfried JM (2012) Catal Today 181:20
Bao X, Muhler M, Pettinger B, Schlögl R, Ertl G (1993) Catal Lett 22:215
Lei Y, Mehmood F, Lee S, Greeley J, Lee B, Seifert S, Winans RE, Elam JW, Meyer RJ, Redfern PC, Teschner D, Schlögl R, Pellin MJ, Curtiss LA, Vajda S (2010) Science 328:224
Nagy A, Mestl G (1999) Appl Catal A Gen 188:337
de Oliveira AL, Wolf A, Schüth F (2001) Catal Lett 73:157
Litter MI (1999) Appl Catal B Environ 23:89
Arabatzis IM, Stergiopoulos T, Bernard MC, Labou D, Neophytides SG, Falaras P (2003) Appl Catal B Environ 42:187
Hirakawa T, Kamat PV (2005) J Am Chem Soc 127:3928
Hu C, Lan YQ, Qu JH, Hu XX, Wang AM (2006) J Phys Chem B 110:4066
Elahifard MR, Rahimnejad S, Haghighi S, Gholami MR (2007) J Am Chem Soc 129:9552
Seery MK, George R, Floris P, Pillai SC (2007) J Photochem Photobiol A 189:258
Awazu K, Fujimaki M, Rockstuhl C, Tominaga J, Murakami H, Ohki Y, Yoshida N, Watanabe T (2008) J Am Chem Soc 130:1676
Xu C, Lai X, Zajac GW, Goodman DW (1997) Phys Rev B 56:13464
Diebold U (2003) Surf Sci Rep 48:53
Thompson TL, Yates JT Jr (2006) Chem Rev 106:4428
Pang CL, Lindsay R, Thornton G (2008) Chem Soc Rev 37:2328
Wendt S, Vang RT, Besenbacher F (2009) In: Vaysieres L (ed) On Solar Hydrogen & Nanotechnology. Wiley, New York, p 467
Dohnálek Z, Lyubinetsky I, Rousseau R (2010) Prog Surf Sci 85:161
Wendt S, Schaub R, Matthiesen J, Vestergaard EK, Wahlström E, Rasmussen MD, Thostrup P, Molina LM, Lægsgaard E, Stensgaard I, Hammer B, Besenbacher F (2005) Surf Sci 598:226
Wendt S, Matthiesen J, Schaub R, Vestergaard EK, Lægsgaard E, Besenbacher F, Hammer B (2006) Phys Rev Lett 96:066107
Wendt S, Sprunger PT, Lira E, Madsen GKH, Li Z, Hansen JØ, Matthiesen J, Blekinge-Rasmussen A, Lægsgaard E, Hammer B, Besenbacher F (2008) Science 320:1755
Lira E, Hansen JØ, Huo P, Bechstein R, Galliker P, Lægsgaard E, Hammer B, Wendt S, Besenbacher F (2010) Surf Sci 604:1945
Lira E, Huo P, Hansen JØ, Rieboldt F, Bechstein R, Wei YY, Streber R, Porsgaard S, Li Z, Lægsgaard E, Wendt S, Besenbacher F (2012) Catal Today 182:25
Tong X, Benz L, Kolmakov A, Chretien S, Metiu H, Buratto SK (2005) Surf Sci 575:60
Luo K, St Clair TP, Lai X, Goodman DW (2000) J Phys Chem B 104:3050
Chen DA, Bartelt MC, Seutter SM, McCarty KF (2000) Surf Sci 464:L708
Benz L, Tong X, Kemper P, Lilach Y, Kolmakov A, Metiu H, Bowers MT, Buratto SK (2005) J Chem Phys 122:081102
Nilius N, Ernst N, Freund H (2001) Chem Phys Lett 349:351
Besenbacher F, Lauritsen JV, Wendt S (2007) Nano Today 2:30
Besenbacher F, Lauritsen JV, Linderoth TR, Lægsgaard E, Vang RT, Wendt S (2009) Surf Sci 603:1315
Hansen JØ, Lira E, Galliker P, Wang J-G, Sprunger PT, Li Z, Lægsgaard E, Wendt S, Hammer B, Besenbacher F (2010) J Phys Chem C 114:16964
Kitsudo Y, Iwamoto A, Matsumoto H, Mitsuhara K, Nishimura T, Takizawa M, Akita T, Maeda Y, Kido Y (2009) Surf Sci 603:2108
Lee S, Fan CY, Wu TP, Anderson SL (2005) Surf Sci 578:5
Lægsgaard E, Besenbacher F, Mortensen K, Stensgaard I (1988) J Microsc 152:663
Lauritsen JV, Besenbacher F (2006) Adv Catal 50:97
Prunier J, Domenichini B, Li Z, Møller PJ, Bourgeois S (2007) Surf Sci 601:1144
Kurtz RL, Stockbauer R, Madey TE, Román E, de Segovia JL (1989) Surf Sci 218:178
Zhang ZM, Jeng SP, Henrich VE (1991) Phys Rev B 43:12004
Lira E, Wendt S, Huo P, Hansen JØ, Streber R, Porsgaard S, Wei YY, Bechstein R, Lægsgaard E, Besenbacher F (2011) J Am Chem Soc 133:6529
Mitsuhara K, Kitsudo Y, Matsumoto H, Visikovskiy A, Takizawa M, Nishimura T, Akita T, Kido Y (2010) Surf Sci 604:548
Borodin A, Reichling M (2011) Phys Chem Chem Phys 13:15442
Mróz S, Jankowski Z (1995) Surf Sci 322:133
Jacobsen J, Nielsen LP, Besenbacher F, Stensgaard I, Lægsgaard E, Rasmussen T, Jacobsen KW, Nørskov JK (1995) Phys Rev Lett 75:489
Vickerman JC (2009) Surface Analysis: The principal techniques. Wiley, Chichester
Powell CJ, Jablonski A NIST Electron Inelastic-Mean-Free-Path Database, Version 11
Madsen GKH, Hammer B (2009) J Chem Phys 130:044704
Woicik JC, Nelson EJ, Kronik L, Jain M, Chelikowsky JR, Heskett D, Berman LE, Herman GS (2002) Phys Rev Lett 89:077401
Wertheim GK, DiCenzo SB, Youngquist SE (1983) Phys Rev Lett 51:2310
Wertheim GK, DiCenzo SB, Buchanan DNE (1986) Phys Rev B 33:5384
Weaver JF, Hoflund GB (1994) J Phys Chem 98:8519
Stracke P, Krischok S, Kempter V (2001) Surf Sci 473:86
Citrin PH, Wertheim GK, Baer Y (1978) Phys Rev Lett 41:1425
Eastman DE, Himpsel FJ, van Der Veen JF (1982) J Vac Sci Technol 20:609
Egelhoff WF Jr (1987) Surf Sci Rep 6:253
Chrétien S, Metiu H (2007) J Chem Phys 126:104701
Hutchings GJ, Hall MS, Carley AF, Landon P, Solsona BE, Kiely CJ, Herzing A, Makkee M, Moulijn JA, Overweg A, Fierro-Gonzalez JC, Guzman J, Gates BC (2006) J Catal 242:71
Kim HJ, Han MK, Lee SM, Hwang DK, Shul YG (2008) Top Catal 47:109
Minati L, Speranza G, Calliari L, Micheli V, Baranov A, Fanchenko S (2008) J Phys Chem A 112:7856
Tanaka A, Takeda Y, Nagasawa T, Takahashi K (2003) Solid State Commun 126:191
Tanaka A, Takeda Y, Imamura M, Sato S (2003) Phys Rev B 68:195415
Duckers K, Bonzel HP (1989) Surf Sci 213:25
Lopez-Salido I, Lim DC, Kim YD (2005) Surf Sci 588:6
Lim DC, Lopez-Salido I, Kim YD (2005) Surf Sci 598:96
Vijay A, Mills G, Metiu H (2003) J Chem Phys 118:6536
Wendt S, Bechstein R, Porsgaard S, Lira E, Hansen JØ, Huo P, Li Z, Hammer B, Besenbacher F (2010) Phys Rev Lett 104:259703
Mitsuhara K, Okumura H, Visikovskiy A, Takizawa M, Kido Y (2012) J Chem Phys 136:124707
Acknowledgments
We acknowledge financial support by the Danish Research Agency, the Strategic Research Council, the Villum Kahn Rasmussen Foundation, the Lundbeck Foundation, the Carlsberg Foundation, and the European Research Council through an Advanced ERC Grant (F.B.). P.T.S. acknowledges support from the EFRC “Center for Atomic Level Catalyst Design” (DOE-DE-SC0001058).
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Lira, E., Hansen, J.Ø., Merte, L.R. et al. Growth of Ag and Au Nanoparticles on Reduced and Oxidized Rutile TiO2(110) Surfaces. Top Catal 56, 1460–1476 (2013). https://doi.org/10.1007/s11244-013-0141-z
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DOI: https://doi.org/10.1007/s11244-013-0141-z