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Poly(1,6-heptadiyne)/ABS functionalized microfibers for hydrophobic applications

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Abstract

We report an electrospun & thermally stable micro-fibers of poly(1,6-heptadiyne) (PHD), modified with ABS. Developed micro-fibers demonstrated hydrophobicity (WCA~145o ± 2o), and exhibited hierarchical surface morphology (confirmed by FESEM analysis). Simulation study showed Chi parameter i.e. χc = 7.88, & free energy of mixing i.e. 4.67 kcal/mol, thereby demonstrating its feasibility for electrospinning. PHD/ABS microfibers demonstrated low ice-adhesion ability, where, it effectively removed frozen water droplets in 8 s from hydrophobic surface, under an air-stream rate of 78 kPa/s. High thermal stability (200 °C), hydrophobicity and low ice-adhesion ability, demonstrate that PHD/ABS microfibers can be effectively used for multifunctional engineering/industrial applications.

Fabrication of poly (1,6-heptadiyne)/ABS microfibers via electrospinning.

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Acknowledgements

The authors are thankful to Dr. C. P. Ramanarayanan, Vice-Chancellor of DIAT (DU), Pune for motivation and support. The authors are also thankful to anonymous reviewers for their valuable suggestions, and comments, which helped in improving the quality of the manuscript.

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Authors and Affiliations

  1. Department of Chemical Sciences, Indian Institute of Science Education & Research, Kolkata, Mohanpur, 741 246, India

    Pawan Kumar & Raja Shunmugam

  2. Nano Surface Texturing Lab, Department of Metallurgical & Materials Engineering, Defence Institute of Advanced Technology (DU), Ministry of Defence, Girinagar, Pune, 411025, India

    Prakash M. Gore, RaviPrakash Magisetty & Balasubramanian Kandasubramanian

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  1. Pawan Kumar
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Kumar, P., Gore, P.M., Magisetty, R. et al. Poly(1,6-heptadiyne)/ABS functionalized microfibers for hydrophobic applications. J Polym Res 27, 14 (2020). https://doi.org/10.1007/s10965-019-1981-4

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