Abstract
ZnO flower/poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) composite films were prepared by spin-coating dimethyl sulfoxide doped PEDOT:PSS on the ZnO flowers grown on glass substrate. The thermoelectric properties of the ZnO flower/PEDOT:PSS composite films were measured at room temperature. As the number of spin coated PEDOT:PSS layer increased, the electrical conductivity of the ZnO flower/PEDOT:PSS composite films increases dramatically from 1-layer (177.3 S/m) to 4-layer (910.4 S/m), however, all the composite films have almost the same Seebeck coefficient (~20–22 μV/K). A maximum power factor of ~0.4 μWm−1 K−2 at room temperature was obtained from the composite film with 4-layer PEDOT:PSS.
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T.C. Harman, P.J. Taylor, M.P. Walsh, B.E. LaForge, Science 297, 2229–2232 (2002)
F.J. DiSalvo, Science 285, 703–706 (1999)
J.P. Heremans, V. Jovovic, E.S. Toberer, A. Saramat, K. Kurosaki, A. Charoenphakdee, S. Yamanaka, G.J. Snyder, Science 321, 554–557 (2008)
K.F. Hsu, S. Loo, F. Guo, W. Chen, J.S. Dyck, C. Uher, T. Hogan, E.K. Polychroniadis, M.G. Kanatzidis, Science 303, 818–821 (2004)
Y. Du, S.Z. Shen, K.F. Cai, P.S. Casey, Prog. Polym. Sci. 37, 820–841 (2012)
G.H. Kim, L. Shao, K. Zhang, K.P. Pipe, Nat. Mater. 12, 719–723 (2013)
K.C. See, J.P. Feser, C.E. Chen, A. Majumdar, J.J. Urban, R.A. Segalman, Nano Lett. 10, 4664–4667 (2010)
S. Xu, Z.L. Wang, Nano Res. 4, 1013–1098 (2011)
M.H. Hong, C.S. Park, S. Shin, H.H. Cho, W.S. Seo, Y.S. Lim, J.K. Lee, H.H. Park, J. Nanomater. 2013, 172504 (2013)
N.N. Wang, H.X. Xin, D. Li, X.J. Li, J. Zhang, X.Y. Qin, J. Phys. Chem. Solids 74, 1811–1815 (2013)
H. Kaga, Y. Kinemuchi, H. Yilmaz, K. Watari, H. Nakano, H. Nakano, S. Tanaka, A. Makiya, Z. Kato, K. Uematsu, Acta Mater. 55, 4753–4757 (2007)
K.F. Cai, E. Muller, C. Drasar, A. Mrotzek, Mater. Sci. Eng., B 104, 45–48 (2003)
T.H. Fang, S.H. Kang, J. Alloy. Compd. 492, 536–542 (2010)
H. Colder, E. Guilmeau, C. Harnois, S. Marinel, R. Retoux, E. Savary, J. Eur. Ceram. Soc. 31, 2957–2963 (2011)
L. Fang, X.F. Yang, L.P. Peng, K. Zhou, F. Wu, Q.L. Huang, C.Y. Kong, J. Supercond. Nov. Magn. 23, 889–892 (2010)
M. Ohtaki, K. Araki, K. Yamamoto, J. Electron. Mater. 38, 1234–1238 (2009)
Y. Du, K.F. Cai, S.Z. Shen, W.D. Yang, P.S. Casey, J. Mater. Sci.: Mater. Electron. 24, 1702–1706 (2013)
Y. Du, K.F. Cai, S. Chen, P. Cizek, T. Lin, ACS Appl. Mater. Interfaces 6, 5735–5743 (2014)
J.P. Liu, X.T. Huang, Y.Y. Li, J.X. Duan, H.H. Ai, Mater. Chem. Phys. 98, 523–527 (2006)
R. Wahab, Y.S. Kim, A. Mishra, S.I. Yun, H.S. Shin, Nanoscale Res. Lett. 5, 1675–1681 (2010)
T. Zhang, Y. Zeng, H.T. Fan, L.J. Wang, R. Wang, W.Y. Fu, H.B. Yang, J. Phys. D Appl. Phys. 42, 045103 (2009)
R.A. Laudise, A.A. Ballman, J. Phys. Chem. 64, 688–691 (1960)
G.X. Tong, F.F. Du, Y. Liang, Q. Hu, R.N. Wu, J.G. Guan, X. Hu, J. Mater. Chem. B 1, 454–463 (2013)
J. Li, J.C. Liu, C.J. Gao, J. Polym. Res. 17, 713–718 (2010)
C.C. Liu, F.X. Jiang, M.Y. Huang, B.Y. Lu, R.R. Yue, J.K. Xu, J. Electron. Mater. 40, 948–952 (2011)
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This work was supported by the National Natural Science Foundation of China (61504081), the Program for Professor of Special Appointment (Young Eastern Scholar Program) at Shanghai Institutions of Higher Learning (QD2015039).
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Du, Y., Cai, K., Shen, S.Z. et al. ZnO flower/PEDOT:PSS thermoelectric composite films. J Mater Sci: Mater Electron 27, 10289–10293 (2016). https://doi.org/10.1007/s10854-016-5111-3
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DOI: https://doi.org/10.1007/s10854-016-5111-3