Abstract
Gold nanoparticles (AuNPs) were synthesized in situ on cotton, one of the most popular cellulose materials, to achieve functionalization. The localized surface plasmon resonance of the AuNPs imparted the cotton fabric with colors, showing good colorfastness to washing and rubbing. Characterization of the surface morphology and chemical composition of the modified cotton fabric confirmed synthesis and coating of the AuNPs on cotton fibers. The relationship between the morphology of the AuNPs and the optical properties of the cotton fabric was analyzed. Acid condition enabled in situ synthesis of AuNPs on cotton. Cotton with AuNPs exhibited significant catalytic activity for reduction of 4-nitrophenol by sodium borohydride, and could be reused in this reaction. Treatment with AuNPs substantially improved the ultraviolet (UV)-blocking ability of the fabric and resulted in cotton with remarkable antibacterial activity. Traditional reactive dyes were applied to the cotton with AuNPs to enhance its color features. The catalytic properties of the AuNPs on the fabric were not influenced by dyeing with traditional dyes. AuNP-treated cotton fabric used as a flexible active substrate showed improved Raman signals of dyes on the fabric.
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Abdel-Fattah TM, Wixtrom A (2014) Catalytic reduction of 4-nitrophenol using gold nanoparticles supported on carbon nanotubes. ECS J Solid State Sci Technol 3:M18–M20. doi:10.1149/2.023404jss
Ai L, Yue H, Jiang J (2012) Environmentally friendly light-driven synthesis of Ag nanoparticles in situ grown on magnetically separable biohydrogels as highly active and recyclable catalysts for 4-nitrophenol reduction. J Mater Chem 22:23447–23453. doi:10.1039/C2JM35616C
Alongi J, Malucelli G (2015) Cotton flame retardancy: state of the art and future perspectives. RSC Adv 5:24239–24263. doi:10.1039/c5ra01176k
Alongi J, Carosio F, Malucelli G (2014) Current emerging techniques to impart flame retardancy to fabrics: an overview. Polym Degrad Stab 106:138–149. doi:10.1016/j.polymdegradstab.2013.07.012
Barnes WL, Dereux A, Ebbesen TW (2003) Surface plasmon subwavelength optics. Nature 424:824–830
Bastús NG, Comenge J, Puntes V (2011) Kinetically controlled seeded growth synthesis of citrate-stabilized gold nanoparticles of up to 200 nm: size focusing versus Ostwald ripening. Langmuir 27:11098–11105. doi:10.1021/la201938u
Bozzi A, Yuranova T, Guasaquillo I, Laub D, Kiwi J (2005) Self-cleaning of modified cotton textiles by TiO2 at low temperatures under daylight irradiation. J Photochem Photobiol A Chem 174:156–164. doi:10.1016/j.jphotochem.2005.03.019
Cady NC, Behnke JL, Strickland AD (2011) Copper-based nanostructured coatings on natural cellulose: nanocomposites exhibiting rapid and efficient inhibition of a multi-drug resistant wound pathogen, A. baumannii, and mammalian cell biocompatibility in vitro. Adv Funct Mater 21:2506–2514. doi:10.1002/adfm.201100123
Chakraborty A, Chakraborty S, Chaudhuri B, Bhattacharjee S (2016) Process engineering studies on gold nanoparticle formation via dynamic spectroscopic approach. Gold Bull 49:75–85. doi:10.1007/s13404-016-0183-7
Chen XQ, Liu YY, Lu HF, Yang HR, Zhou XA, Xin JH (2010) In-situ growth of silica nanoparticles on cellulose and application of hierarchical structure in biomimetic hydrophobicity. Cellulose 17:1103–1113. doi:10.1007/s10570-010-9445-3
Corma A, Garcia H (2008) Supported gold nanoparticles as catalysts for organic reactions. Chem Soc Rev 37:2096–2126. doi:10.1039/b707314n
Cui Y, Zhao Y, Tian Y, Zhang W, Lu X, Jiang X (2012) The molecular mechanism of action of bactericidal gold nanoparticles on Escherichia coli. Biomaterials 33:2327–2333. doi:10.1016/j.biomaterials.2011.11.057
Daniel MC, Astruc D (2004) Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem Rev 104:293–346. doi:10.1021/cr030698+
Dhineshbabu NR, Arunmetha S, Manivasakan P, Karunakaran G, Rajendran V (2016) Enhanced functional properties of cotton fabrics using TiO2/SiO2 nanocomposites. J Ind Text 45:674–692. doi:10.1177/1528083714538684
Dong H, Hinestroza JP (2009) Metal nanoparticles on natural cellulose fibers: electrostatic assembly and in situ synthesis. ACS Appl Mater Interfaces 1:797–803. doi:10.1021/am800225j
Edwards HGM, Farwell DW, Webster D (1997) FT Raman microscopy of untreated natural plant fibres. Spectrochim Acta A 53:2383–2392. doi:10.1016/s1386-1425(97)00178-9
El-Naggar ME, Shaheen TI, Zaghloul S, El-Rafie MH, Hebeish A (2016) Antibacterial activities and uv protection of the in situ synthesized titanium oxide nanoparticles on cotton fabrics. Ind Eng Chem Res 55:2661–2668. doi:10.1021/acs.iecr.5b04315
El-Naggar ME, Hassabo AG, Mohamed AL, Shaheen TI (2017) Surface modification of SiO2 coated ZnO nanoparticles for multifunctional cotton fabrics. J Colloid Interface Sci 498:413–422. doi:10.1016/j.jcis.2017.03.080
El-Shishtawy RM, Asiri AM, Abdelwahed NAM, Al-Otaibi MM (2011) In situ production of silver nanoparticle on cotton fabric and its antimicrobial evaluation. Cellulose 18:75–82. doi:10.1007/s10570-010-9455-1
Emam HE, El-Hawary NS, Ahmed HB (2017) Green technology for durable finishing of viscose fibers via self-formation of AuNPs. Int J Biol Macromol 96:697–705. doi:10.1016/j.ijbiomac.2016.12.080
Fateixa S, Wilhelm M, Nogueira HIS, Trindade T (2016) SERS and Raman imaging as a new tool to monitor dyeing on textile fibres. J Raman Spectrosc 47:1239–1246. doi:10.1002/jrs.4947
Goia D, Matijević E (1999) Tailoring the particle size of monodispersed colloidal gold. Colloids Surf A 146:139–152. doi:10.1016/S0927-7757(98)00790-0
Gorjanc M, Bukosek V, Gorensek M, Mozetic M (2010) CF4 plasma and silver functionalized cotton. Text Res J 80:2204–2213. doi:10.1177/0040517510376268
Herves P, Perez-Lorenzo M, Liz-Marzan LM, Dzubiella J, Lu Y, Ballauff M (2012) Catalysis by metallic nanoparticles in aqueous solution: model reactions. Chem Soc Rev 41:5577–5587. doi:10.1039/C2CS35029G
Ji X, Song X, Li J, Bai Y, Yang W, Peng X (2007) Size control of gold nanocrystals in citrate reduction: the third role of citrate. J Am Chem Soc 129:13939–13948. doi:10.1021/ja074447k
Kimling J, Maier M, Okenve B, Kotaidis V, Ballot H, Plech A (2006) Turkevich method for gold nanoparticle synthesis revisited. J Phys Chem B 110:15700–15707. doi:10.1021/jp061667w
Komeily-Nia Z, Montazer M, Latifi M (2013) Synthesis of nano copper/nylon composite using ascorbic acid and CTAB. Colloids Surf A Physicochem Eng Asp 439:167–175. doi:10.1016/j.colsurfa.2013.03.003
Kumar A, Mandal S, Selvakannan PR, Pasricha R, Mandale AB, Sastry M (2003) Investigation into the interaction between surface-bound alkylamines and gold nanoparticles. Langmuir 19:6277–6282. doi:10.1021/la034209c
Leng BX, Shao ZZ, de With G, Ming WH (2009) Superoleophobic cotton textiles. Langmuir 25:2456–2460. doi:10.1021/la8031144
Leona M, Lombardi JR (2007) Identification of berberine in ancient and historical textiles by surface-enhanced Raman scattering. J Raman Spectrosc 38:853–858. doi:10.1002/jrs.1726
Leona M, Stenger J, Ferloni E (2006) Application of surface-enhanced Raman scattering techniques to the ultrasensitive identification of natural dyes in works of art. J Raman Spectrosc 37:981–992. doi:10.1002/jrs.1582
Liang M, Su R, Huang R, Qi W, Yu Y, Wang L, He Z (2014) Facile in situ synthesis of silver nanoparticles on procyanidin-grafted eggshell membrane and their catalytic properties. ACS Appl Mater Interfaces 6:4638–4649. doi:10.1021/am500665p
Liu YY, Wang XW, Qi KH, Xin JH (2008) Functionalization of cotton with carbon nanotubes. J Mater Chem 18:3454–3460. doi:10.1039/b801849a
Liu J et al (2016) Surface enhanced Raman scattering (SERS) fabrics for trace analysis. Appl Surf Sci 386:296–302. doi:10.1016/j.apsusc.2016.05.150
Medina-Ramirez I, Gonzalez-Garcia M, Palakurthi S, Liu J (2012) Application of nanometals fabricated using green synthesis in cancer diagnosis and therapy. In: Kidwai M (ed) Green chemistry—environmentally benign approaches. InTech, Rijeka. doi:10.5772/36957
Meleiro PP, Garcia-Ruiz C (2016) Spectroscopic techniques for the forensic analysis of textile fibers. Appl Spectrosc Rev 51:258–281. doi:10.1080/05704928.2015.1132720
Mohamed AL, El-Naggar ME, Shaheen TI, Hassabo AG (2017) Laminating of chemically modified silan based nanosols for advanced functionalization of cotton textiles. Int J Biol Macromol 95:429–437. doi:10.1016/j.ijbiomac.2016.10.082
Montazer M, Alimohammadi F, Shamei A, Rahimi MK (2012) In situ synthesis of nano silver on cotton using Tollens’ reagent. Carbohydr Polym 87:1706–1712. doi:10.1016/j.carbpol.2011.09.079
Panigrahi S et al (2007) Synthesis and size-selective catalysis by supported gold nanoparticles: study on heterogeneous and homogeneous catalytic process. J Phys Chem C 111:4596–4605. doi:10.1021/jp067554u
Pinto RJB, Marques P, Martins MA, Neto CP, Trindade T (2007) Electrostatic assembly and growth of gold nanoparticles in cellulosic fibres. J Colloid Interface Sci 312:506–512. doi:10.1016/j.jcis.2007.03.043
Prasad V, Arputharaj A, Bharimalla AK, Patil PG, Vigneshwaran N (2016) Durable multifunctional finishing of cotton fabrics by in situ synthesis of nano-ZnO. Appl Surf Sci 390:936–940. doi:10.1016/j.apsusc.2016.08.155
Sadr FA, Montazer M (2014) In situ sonosynthesis of nano TiO2 on cotton fabric. Ultrason Sonochem 21:681–691. doi:10.1016/j.ultsonch.2013.09.018
Saha K, Agasti SS, Kim C, Li X, Rotello VM (2012) Gold nanoparticles in chemical and biological sensing. Chem Rev 112:2739–2779. doi:10.1021/cr2001178
Shaheen TI, El-Naggar ME, Abdelgawad AM, Hebeish A (2016) Durable antibacterial and UV protections of in situ synthesized zinc oxide nanoparticles onto cotton fabrics. Int J Biol Macromol 83:426–432. doi:10.1016/j.ijbiomac.2015.11.003
Tang B, Zhang M, Hou X, Li J, Sun L, Wang X (2012) Coloration of cotton fibers with anisotropic silver nanoparticles. Ind Eng Chem Res 51:12807–12813. doi:10.1021/ie3015704
Tang B, Kaur J, Sun L, Wang X (2013) Multifunctionalization of cotton through in situ green synthesis of silver nanoparticles. Cellulose 20:3053–3065. doi:10.1007/s10570-013-0027-z
Tang B, Sun L, Kaur J, Yu Y, Wang X (2014) In-situ synthesis of gold nanoparticles for multifunctionalization of silk fabrics. Dyes Pigm 103:183–190. doi:10.1016/j.dyepig.2013.12.008
Tang B, Li JL, Fan LP, Wang XG (2015a) Facile synthesis of silver submicrospheres and their applications. RSC Adv 5:98293–98298. doi:10.1039/c5ra18513k
Tang B et al (2015b) Functional application of noble metal nanoparticles in situ synthesized on ramie fibers. Nanoscale Res Lett. doi:10.1186/s11671-015-1074-1
Tang B, Zhou X, Zeng T, Lin X, Zhou J, Ye Y, Wang X (2017) In situ synthesis of gold nanoparticles on wool powder and their catalytic application. Materials 10:295
Velleste R, Teugjas H, Valjamae P (2010) Reducing end-specific fluorescence labeled celluloses for cellulase mode of action. Cellulose 17:125–138. doi:10.1007/s10570-009-9356-3
Wadhwani P, Heidenreich N, Podeyn B, Burck J, Ulrich AS (2017) Antibiotic gold: tethering of antimicrobial peptides to gold nanoparticles maintains conformational flexibility of peptides and improves trypsin susceptibility. Biomater Sci 5:817–827. doi:10.1039/c7bm00069c
Wang S, Qian K, Bi X, Huang W (2009) Influence of speciation of aqueous HAuCl4 on the synthesis, structure, and property of Au colloids. J Phys Chem C 113:6505–6510. doi:10.1021/jp811296m
Wu XD, Lu CH, Zhou ZH, Yuan GP, Xiong R, Zhang XX (2014) Green synthesis and formation mechanism of cellulose nanocrystal-supported gold nanoparticles with enhanced catalytic performance. Environ Sci Nano 1:71–79. doi:10.1039/c3en00066d
Wu MC, Ma BH, Pan TZ, Chen SS, Sun JQ (2016) Silver-nanoparticle-colored cotton fabrics with tunable colors and durable antibacterial and self-healing superhydrophobic properties. Adv Funct Mater 26:569–576. doi:10.1002/adfm.201504197
Wuithschick M et al (2015) Turkevich in new robes: key questions answered for the most common gold nanoparticle synthesis. ACS Nano 9:7052–7071. doi:10.1021/acsnano.5b01579
Yu Chang S-S, Lee C-L, Wang CRC (1997) Gold nanorods: electrochemical synthesis and optical properties. J Phys Chem B 101:6661–6664. doi:10.1021/jp971656q
Zaffino C, Ngo HT, Register J, Bruni S, Vo-Dinh T (2016) “Dry-state” surface-enhanced Raman scattering (SERS): toward non-destructive analysis of dyes on textile fibers. Appl Phys A Mater Sci Process. doi:10.1007/s00339-016-0209-2
Zhang P, Li Y, Wang D, Xia H (2016) High-yield production of uniform gold nanoparticles with sizes from 31 to 577 nm via one-pot seeded growth and size-dependent SERS property. Part Part Syst Charact 33:924–932. doi:10.1002/ppsc.201600188
Zhao Y, Huang YC, Zhu H, Zhu QQ, Xia YS (2016) Three-in-one: sensing, self-assembly, and cascade catalysis of cyclodextrin modified gold nanoparticles. J Am Chem Soc 138:16645–16654. doi:10.1021/jacs.6b07590
Zorko M, Vasiljevic J, Tomsic B, Simoncic B, Gaberscek M, Jerman I (2015) Cotton fiber hot spot in situ growth of Stober particles. Cellulose 22:3597–3607. doi:10.1007/s10570-015-0762-4
Acknowledgments
This research was supported by the National Natural Science Foundation of China (NSFC 51403162 and 51273153). We would also like to acknowledge research support from the MoE Innovation Team Project in Biological Fibers Advanced Textile Processing and Clean Production (no. IRT13086).
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Tang, B., Lin, X., Zou, F. et al. In situ synthesis of gold nanoparticles on cotton fabric for multifunctional applications. Cellulose 24, 4547–4560 (2017). https://doi.org/10.1007/s10570-017-1413-8
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DOI: https://doi.org/10.1007/s10570-017-1413-8