Abstract
The electrochemical behavior of C60-Pd polymer formed under electrochemical conditions and by the chemical synthesis was examined. In these polymers, fullerene moieties are covalently bonded to palladium atoms to form a polymeric network. Both materials deposited at the electrode surface show electrochemical activity at negative potentials due to the reduction of fullerene cage. Electrochemically formed thin polymeric films exhibit much more reversible voltammetric response in comparison to chemically synthesized polymers. The morphology and electrochemical behavior of chemically synthesized C60-Pd polymer depend on the composition of grown solution. Chemical polymerization results in formation of large, ca. 50 μm, crystallic superficial structures that are composed of regular spherical particles with a diameter of 150 nm. The capacitance properties of C60-Pd films were investigated by cyclic voltammetry and faradaic impedance spectroscopy. Specific capacitance of chemically formed films depends on the conditions of film formation. The best capacitance properties was obtained for films containing 1:3 fullerene to Pd molar ratio. For these films, specific capacitance of 35 Fg−1 was obtained in acetonitrile containing (n-C4H9)4NClO4. This value is much lower in comparison to the specific capacitance of electrochemically formed C60-Pd film.
Similar content being viewed by others
References
Frackowiak E, Beguin F (2002) Carbon 40:1775–1787
Jurewicz K, Delpeux S, Bertagna V, Beguin F, Frackowiak E (2001) Chem Phys Lett 347:36–40
Zhang Y, Feng H, Wu X, Wang L, Zhang A, Xia T, Dong H, Li X, Zhang L (2009) Int J Hydrogen Energy 34:4889–4899
Ryu KS, Lee YG, Hong YS, Park YJ, Wu X, Kim KM, Kang MG, Park NG, Chang SH (2004) Electrochim Acta 50:843–847
Fan LZ, Maier J (2006) Electrochem Commun 8:937–940
Kim BC, Ko JM, Wallace GG (2008) J Power Sources 177:665–668
Kim BC, Kwon JS, Ko JM, Park JH, Too CO, Wallace GG (2010) Synth Met 160:94–98
Zhai Y, Dou Y, Zhao D, Fulvio PF, Mayes RT, Dai S (2011) Adv Mater 23:4828–4850
Inamdar AI, Kim YS, Sohn JS, Im H, Kim H, Kim DY, Kalubarme RS, Park C (2011) Journal of the Korean Physical Society 59:145–149
Sivaraman P, Kushwaha RK, Shashidhara K, Hande VR, Thakur AP, Samui AB, Khandpekar MM (2010) Electrochim Acta 55:2451–2456
Plesu N, Kellenberger A, Mihali M, Vaszilcsin N (2010) J Non-Cryst Solids 356:1081–1088
Liu J, Zhou M, Fan LZ, Li P, Qu X (2010) Electrochim Acta 55:5819–5822
Warren MR, Madden JD (2006) Synth Met 156:724–730
Marchesi LFQP, Simões FR, Pocrifka LA, Pereira EC (2011) J Phys Chem B 115:9570–9575
Sharma RK, Rastogi AC, Desu SB (2008) Electrochem Commun 10:268–272
Dubal DP, Lee SH, Kim JG, Kim WB, Lokhande CD (2012) J Mater Chem 22:3044–3052
Song HK, Palmore GTR (2006) Adv Mater 18:1764–1768
Gnanakan SRP, Rajasekhar M, Subramania A (2009) Int J Electrochem Sci 4:1289–1301
Liu L, Tian F, Wang X, Yang Z, Zhou M, Wang X (2012) React Funct Polym 72:45–49
Suarez-Herrera MF, Feliu JM (2009) J Phys Chem B 113:1899–1905
Oh KW, Park HJ, Kim SH (2004) J Appl Polym Sci 91:3659–3666
Moraes SR, Huerta-Vilca D, Motheo AJ (2004) Eur Polym J 40:2033–2041
Bazzaoui M, Martins L, Bazzaoui EA, Martins JI (2002) Electrochim Acta 47:2953–2962
Tourillon G, Garnier F (1982) J Electroanal Chem 135:173–178
Yamamoto T, Sanechika K, Yamamoto A (1980) J Polym Sci Polym Phys 30:19–24
Frackowiak E, Khomenko V, Jurewicz K, Lota K, Béguin F (2006) J Power Sources 153:413–418
Laridjani M, Pouget JP, Scherr EM, MacDiarmid AG, Jozefowicz ME, Epstein AJ (1992) Macromolecules 25:4106–4113
Kinlen PJ, Liu J, Ding Y, Graham CR, Remsen EE (1998) Macromolecules 31:1735–1744
Echegoyen L, Echegoyen LE (1998) Acc Chem Res 31:593–601
Xie Q, Pérez-Cordero E, Echegoyen L (1992) J Am Chem Soc 114:3978–3980
Yanilkin VV, Gubskaya VP, Morozov VI, Nastapova NV, Zverev VV, Berdnikov EA, Nuretdinov IA (2003) Russ J Electrochem 39:1285–1303
Giacalone F, Martin N (2006) Chem Rev 106:5136–5190
Winkler K, Balch AL, Kutner W (2006) J Solid State Electrochem 10:761–784
Winkler K, Balch AL (2006) C R Chimie 9:928–943
Benincori T, Brenna E, Sannicolo F, Trimarco L, Zotti G, Sozzani P (1996) Angew Chem Int Ed Engl 35:648–651
Cravino A, Zerza G, Neugebauer H, Maggini M, Bucella S, Menna E, Svensson M, Andersson MR, Brabec CJ, Sariciftici NS (2002) J Phys Chem B 106:70–76
Carvino A, Sarciftici NS (2002) J Mater Chem 12:1931–1943
Cravino A, Zerza G, Maggini M, Bucella S, Svensson M, Andersson M R, Neugebauer H, Sariciftici NS (2000) Chem Commun 2487–2488
Cravino A, Zerza G, Neugebauer H, Bucella S, Maggini M, Menna E, Scorrano G, Svensson M, Andersson MR, Sariciftici NS (2001) Synth Met 121:1555–1556
Anderson HL, Boudou C, Diederich F, Gisselbrecht JP, Gross M, Seiler P (1994) Angew Chem Int Ed Engl 33:1628–1632
Fedurco M, Costa DA, Balch AL, Fawcett WR (1995) Angew Chem Int Ed Engl 34:194–196
Winkler K, Costa DA, Balch AL, Fawcett WR (1995) J Phys Chem 99:17431–17436
Winkler K, Costa DA, Fawcett WR, Balch AL (1997) Adv Mater 9:153–156
Krinichnaya EP, Moravsky AP, Efimov O, Sobczak JW, Winkler K, Kutner W, Balch AL (2005) J Mater Chem 15:1468–1476
Balch AL, Costa DA, Winkler K (1998) J Am Chem Soc 120:9614–9620
Winkler K, de Bettencourt-Dias A, Balch AL (1999) Chem Mater 11:2265–2273
Winkler K, Noworyta K, Kutner W, Balch AL (2000) J Electrochem Soc 147:2597–2603
Winkler K, de Bettencourt-Dias A, Balch AL (2000) Chem Mater 12:1386–1392
Winkler K, Noworyta K, de Bettencourt-Dias A, Sobczak JW, Wu CT, Chen LC, Kutner W, Balch AL (2003) J Mater Chem 13:518–525
Hayashi A, de Bettencourt-Dias A, Winkler K, Balch AL (2002) J Mater Chem 12:2116–2122
Plonska ME, de Bettencourt-Dias A, Balch AL, Winkler K (2003) Chem Mater 15:4122–4131
Plonska ME, Makar A, Winkler K, Balch AL (2004) Pol J Chem 78:1431–1447
Winkler K, Plonska-Brzezinska ME, Gadde S, D’Souza F, Balch AL (2006) Electroanalysis 18:841–848
Wysocka-Żołopa M, Winkler K, Caballero R, Langa F (2011) Electrochim Acta 56:5566–5574
Nagashima H, Nakaoka A, Saito Y, Kato M, Kawanishi T, Lotha K (1992) J Chem Soc Chem Commun 377–379
Nagashima H, Yamaguchi H, Kato Y, Saito Y, Haga M A, Itoh K (1993) Chem Lett 22:2153–2156
Winkler K, Grodzka E, D’Souza F, Balch AL (2007) J Electrochem Soc 154:K1–K10
Grodzka E, Nieciecka M, Winkler K (2008) J Solid State Electrochem 12:215–223
Jehoulet C, Obeng YS, Kim YT, Zhou F, Bard AJ (1992) J Am Chem Soc 114:4237–4247
Xu F, Zheng G, Wu D, Liang Y, Li Z, Fu R (2010) Phys Chem Chem Phys 12:3270–3275
Ren X, Pickup PGJ (1992) J Electrochem Soc 139:2097–2105
Acknowledgments
This work was financially supported by the National Center of Science (project no. 2011/01/B/ST5/0627 to KW). We thanks to E. Zambrzycka for ETAAS determination of palladium concentration.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Brancewicz, E., Grądzka, E. & Winkler, K. Comparison of electrochemical properties of two-component C60-Pd polymers formed under electrochemical conditions and by chemical synthesis. J Solid State Electrochem 17, 1233–1245 (2013). https://doi.org/10.1007/s10008-012-1982-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-012-1982-2