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Understanding the Co-precipitation Mechanisms of Al3(Sc, Zr) with Strengthening Phases in Al–Cu–Li Model Alloys

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Abstract

The addition of scandium (Sc) is known to be beneficial to the properties of aluminium alloys. Sc has a significant impact on the strength, especially when combined with zirconium (Zr) where nano-size Al3(Sc, Zr) dispersoids are formed. However, to date the extraction of Sc from its oxide has been too expensive to promote its use on the industrial scale. New extraction methods have made the process more cost-effective. So far, there has been only limited research done concerning the effect of Sc in Al–Cu–Li alloys. Interaction between the Al3(Sc, Zr) dispersoids and other precipitate phases containing copper (Cu) and/or lithium (Li) have been rarely studied. In this study, the impact of Sc and Zr on precipitation and further the properties of Al–Cu–Li alloys is investigated. Mechanical properties were examined by quasi-static tensile tests. Using TEM, the morphology and size of dispersoids and precipitates were examined.

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References

  1. Dursun, T. and C. Soutis, Recent developments in advanced aircraft aluminium alloys. Materials & Design, 2014. 56: p. 862–871.

    Article  CAS  Google Scholar 

  2. Boyer, R., et al., Materials considerations for aerospace applications. MRS Bulletin, 2015. 40(12): p. 1055–1066.

    Article  Google Scholar 

  3. Warner, T. Recently-developed aluminium solutions for aerospace applications. in Materials Science Forum. 2006. Trans Tech Publ.

    Article  CAS  Google Scholar 

  4. Braun, R. Investigation on microstructure and corrosion behaviour of 6XXX series aluminium alloys. in Materials science forum. 2006. Trans Tech Publ.

    Google Scholar 

  5. Gupta, R.K., et al., Development and characterization of Al–Li alloys. Materials Science and Engineering: A, 2006. 420(1–2): p. 228–234.

    Article  Google Scholar 

  6. Immarigeon, J.P., et al., Microstructural Characterization of Lightweight Structural Materials TransportationLightweight materials for aircraft applications. Materials Characterization, 1995. 35(1): p. 41–67.

    Article  CAS  Google Scholar 

  7. Rioja, R.J. and J. Liu, The Evolution of Al-Li Base Products for Aerospace and Space Applications. Metallurgical and Materials Transactions A, 2012. 43(9): p. 3325–3337.

    Article  CAS  Google Scholar 

  8. Schmitz, C., Handbook of Aluminium Recycling. 2006: Vulkan-Verlag.

    Google Scholar 

  9. Haasen, P. and B.L. Mordike, Physical Metallurgy. 1996: Cambridge University Press.

    Google Scholar 

  10. Dorin, T., et al., Effect of Sc and Zr additions on the microstructure/strength of Al-Cu binary alloys. Materials Science and Engineering: A, 2017.

    Article  CAS  Google Scholar 

  11. Radmilovic, V., et al., Monodisperse Al 3 (LiScZr) core/shell precipitates in Al alloys. Scripta Materialia, 2008. 58(7): p. 529–532.

    Article  CAS  Google Scholar 

  12. Gottstein, G., Physikalische Grundlagen der Materialkunde. 2007: Springer Berlin Heidelberg.

    Google Scholar 

  13. K. E. Knipling, D. N. Seidman and D. C. Dunand. Ambient-and high-temperature mechanical properties of isochronally aged Al–0.06 Sc, Al–0.06 Zr and Al–0.06 Sc–0.06 Zr (at.%) alloys. Acta Mater., vol. 59, no. 3, pp. 943–954, 2011.

    Google Scholar 

  14. S.-L. Lee, C.-T. Wu, and Y.-D. Chen, Effects of Minor Sc and Zr on the Microstructure and Mechanical Properties of Al-4.6Cu-0.3 Mg-0.6Ag Alloys, J. Mater. Eng. Perform., vol. 24, no. 3, pp. 1165–1172, 2015.

    Google Scholar 

  15. Häusler, Ines, et al. Precipitation of T1 and θ′ Phase in Al-4Cu-1Li-0.25 Mn During Age Hardening: Microstructural Investigation and Phase-Field Simulation. Materials 10.2 (2017): 117.

    Article  Google Scholar 

  16. Ringer, S. P., B. C. Muddle, and I. J. Polmear. Effects of cold work on precipitation in Al-Cu-Mg-(Ag) and Al-Cu-Li-(Mg-Ag) alloys. Metallurgical and Materials Transactions A 26.7 (1995): 1659–1671.

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to acknowledge Clean TeQ for providing in-kind Al-Sc master alloys. Dave Gray is warmly thanked for casting the alloys used in this project. Deakin University’s Advanced Characterization Facility is acknowledged for use of the Jeol 2100F transmission electron microscope.

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Correspondence to Katrin Mester .

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Mester, K., Rouxel, B., Langan, T., Lamb, J., Barnett, M., Dorin, T. (2018). Understanding the Co-precipitation Mechanisms of Al3(Sc, Zr) with Strengthening Phases in Al–Cu–Li Model Alloys. In: Martin, O. (eds) Light Metals 2018. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72284-9_32

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