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Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications pp 375–401Cite as

Kinetics of Nonequilibrium Transition in Spin-Crossover Compounds

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 156))

Abstract

This chapter is devoted to an analysis of spin-crossover system dynamics in the framework of Ising-like mechanoelastic model and macroscopic phenomenological model. Based on mechanoelastic model, the intermolecular interaction between spin-crossover sites and cooperative effects in materials has been studied. For light-induced spin-transition the relaxation curves has been calculated by Monte Carlo methods. The additive and multiplicative noise influence on transition phenomena following from system contact with environment was found within macroscopic description of spin-crossover system dynamics in Langevin framework and the corresponding Fokker-Planck equation. The mean first passage time from metastable state driven by colored noise was calculated by using the Kramers-like approximation. In addition, it is shown that transitions can be controlled by a parameter that governs relaxation flow, intensity of light and noise intensity.

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Acknowledgements

Research of Iu. G. and A. M. was supported in part by the an Erasmus Mundus mobility program EMERGE, co-financed by the European Commission in the framework of the Erasmus Mundus programme. Iu. G. and A. M. thank the scientific group of Prof. Alexandru Stancu for the hospitality at the Alexandru Ioan Cuza University of Iasi while this work was in progress.

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Authors and Affiliations

  1. Chernivtsi National University, Kotsubynski Str., Nr. 2, Chernivtsi, 58012, Ukraine

    Iurii Gudyma & Artur Maksymov

  2. Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506, Iasi, Romania

    Cristian Enachescu

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  1. Iurii Gudyma
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  2. Cristian Enachescu
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Correspondence to Iurii Gudyma .

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Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kiev, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kiev, Ukraine

    Leonid Yatsenko

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Gudyma, I., Enachescu, C., Maksymov, A. (2015). Kinetics of Nonequilibrium Transition in Spin-Crossover Compounds. In: Fesenko, O., Yatsenko, L. (eds) Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications. Springer Proceedings in Physics, vol 156. Springer, Cham. https://doi.org/10.1007/978-3-319-06611-0_29

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