Skip to main content

Optimised Composition and Process Design to Develop Sc-Enhanced Wrought Al-Si Alloys

  • Conference paper
  • First Online:
  • 296 Accesses

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

In a number of aluminium (Al ) alloys to date, scandium (Sc) additions have revealed a significant and beneficial effect on strengthening, even when added in small quantities. However, the strengthening response of the ternary Al -Si-Sc alloy system has been hampered by an apparent unfavourable interaction between silicon (Si) and Sc; forming the deleterious V-phase (AlSc2Si2) and thus limiting the allowable Si-content to ~0.15 wt.%. In this study, phase diagrams were calculated using CALPHAD and utilised to design Al -Si-Sc alloy compositions and heat treatment parameters. The Al -Si-Sc alloys were processed using a conventional route of wrought aluminium semi-products. A hardness improvement of up to 30% was achieved for the alloys containing Si as high as 0.8 wt.% in the F-temper. The improved hardness was mainly attributed to the homogeneously distributed, coherent, (Al ,Si)3Sc nano-dispersoids in the α-Al matrix formed during a low temperature annealing treatment and retained in the F-temper condition.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   299.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD   449.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. I. Polmear, Light alloys: Metallurgy of the light metals, Edward Arnold, United Kingdom, 1995.

    Google Scholar 

  2. Z. Ahmad, A. Ul-Hamid, B. Abdul Aleem, The corrosion behavior of scandium alloyed Al 5052 in neutral sodium chloride solution, Corros. Sci. 43 (2001) 1227–1243. https://doi.org/10.1016/s0010-938x(00)00147-5.

  3. M. Cavanaugh, N. Birbilis, R. Buchheit, F. Bovard, Investigating localized corrosion susceptibility arising from Sc containing intermetallic Al3Sc in high strength Al-alloys, Scr. Mater. 56 (2007) 995–998. https://doi.org/10.1016/j.scriptamat.2007.01.036.

  4. S. Iwamura, Y. Miura, Loss in coherency and coarsening behavior of Al3Sc precipitates, Acta Mater. 52 (2004) 591–600. https://doi.org/10.1016/j.actamat.2003.09.042.

  5. L. Toropova, D. Eskin, M. Kharakterova, T. Dobatkina, Advanced aluminium alloys containing Scandium, Taylor & Francis Group, London & New York, 1998.

    Google Scholar 

  6. V. Davydov, T. Rostova, V. Zakharov, Y. Filatov, V. Yelagin, Scientific principles of making an alloying addition of scandium to aluminium alloys, Mater. Sci. Eng. A. 280 (2000) 30–36. https://doi.org/10.1016/s0921-5093(99)00652-8.

  7. T. Dorin, M. Ramajayam, A. Vahid, T. Langan, Aluminium Scandium Alloys, in: Fundam. Alum. Metall., Woodhead Publishing, United Kingdom, 2018: pp. 439–494.

    Google Scholar 

  8. L. Rokhlin, N. Bochvar, O. Rybal’chenko, I. Tarytina, A. Sukhanov, Phase equilibria in aluminum-rich Al-Sc-Si alloys during solidification, Russ. Metall. 2012(7) (2012) 606–611. https://doi.org/10.1134/s0036029512070129.

  9. M. Kharakterova, D. Eskin, L. Toropova, Precipitation hardening in ternary alloys of the Al-Sc-Cu and Al-Sc-Si systems, Acta Met. Mater. 42(7) (1994) 2285–2290.

    Google Scholar 

  10. C. Booth-Morrison, Z. Mao, M. Diaz, D. Dunand, C. Wolverton, Role of silicon in accelerating the nucleation of Al3(Sc,Zr) precipitates in dilute Al–Sc–Zr alloys, Acta Mater. 60 (2012) 4740–4752. https://doi.org/10.1016/j.actamat.2012.05.036.

  11. N. Vo, D. Dunand, D. Seidman, Improving aging and creep resistance in a dilute Al-Sc alloy by microalloying with Si, Zr and Er, Acta Mater. 63 (2014) 73–85. https://doi.org/10.1016/j.actamat.2013.10.008.

  12. Q. Yao, Elastic Properties and Electronic Structure of L12 (Al,Si)3Sc, Adv. Mater. Res. 284–286 (2011) 1987–1990. https://doi.org/10.4028/www.scientific.net/amr.284-286.1987.

  13. G. Du, J. Deng, Y. Wang, D. Yan, L. Rong, Precipitation of (Al,Si)3Sc in an Al-Sc-Si alloy, Scr. Mater. 61 (2009) 532–535. https://doi.org/10.1016/j.scriptamat.2009.05.014.

  14. T. Dorin, M. Ramajayam, T.J. Langan, Effects of Mg, Si, and Cu on the formation of the Al3Sc/Al3Zr dispersoids, in: 6th Int. Alum. Alloy. Conf., Canadian Institute of Mining, Metallurgy & Petroleum, 2018.

    Google Scholar 

  15. H. Jo, S. Fujikawa, Kinetics of precipitation in Al-Sc alloys and low temperature solid solubility of scandium in aluminium studied by electrical resistivity measurements, Mater. Sci. Eng. A. 171 (1993) 151–161.

    Google Scholar 

  16. J. Royset, N. Ryum, Scandium in aluminium alloys, Int. Mater. Rev. 50(1) (2005) 19–44. https://doi.org/10.1179/174328005x14311.

  17. T. Dorin, M. Ramajayam, J. Lamb, T. Langan, Effect of Sc and Zr additions on the microstructure/strength of Al-Cu binary alloys, Mater. Sci. Eng. A. 707 (2017) 58–64. https://doi.org/10.1016/j.msea.2017.09.032.

  18. B. Li, Q. Pan, Z. Yin, Characterization of hot deformation behavior of as-homogenized Al–Cu–Li–Sc–Zr alloy using processing maps, Mater. Sci. Eng. A. 614 (2014) 199–206. https://doi.org/10.1016/j.msea.2014.07.031.

  19. V. Jindal, P. De, K. Venkateswarlu, Effect of Al3Sc precipitates on the work hardening behavior of aluminum-scandium alloys, Mater. Lett. 60 (2006) 3373–3375. https://doi.org/10.1016/j.matlet.2006.03.017.

  20. E. Marquis, D. Seidman, Nanoscale structural evolution of Al3Sc precipitates in Al(Sc) alloys, Acta Mater. 49 (2001) 1909–1919. https://doi.org/10.1016/s1359-6454(01)00116-1.

  21. J. Royset, N. Ryum, Kinetics and mechanisms of precipitation in an Al-0.2 wt. % Sc alloy, Mater. Sci. Eng. A. 396 (2005) 409–422. https://doi.org/10.1016/j.msea.2005.02.015.

  22. D. Williams, B. Carter, Transmission electron microscopy: Part 1- Basics, 2nd ed., Springer, New York, 2009.

    Google Scholar 

  23. W. Zhang, Y. Ye, L. He, P. Li, X. Feng, L. Novikov, Dynamic response and microstructure control of Al-Sc binary alloy under high-speed impact, Mater. Sci. Eng. A. 578 (2013) 35–45. https://doi.org/10.1016/j.msea.2013.04.067.

Download references

Acknowledgements

The authors acknowledge the use of facilities within the Monash Centre for Electron Microscopy. The MGS (Monash Graduate Scholarship), IMPRS (International Monash Postgraduate Research Scholarship) for the financial support required to conduct this work. The authors would like to acknowledge Clean TeQ Ltd. for providing in-kind Al-Sc master alloys.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jayshri Dumbre .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Dumbre, J., Langan, T., Dorin, T., Birbilis, N. (2019). Optimised Composition and Process Design to Develop Sc-Enhanced Wrought Al-Si Alloys. In: Chesonis, C. (eds) Light Metals 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05864-7_179

Download citation

Publish with us

Policies and ethics